Aerogel Spring‐Back Correlates with Strain Recovery: Effect of Silica Concentration and Aging
نویسندگان
چکیده
Silica aerogels display exceptional properties and great application potential, with a mature market in thermal insulation. Both supercritical drying (SCD) ambient pressure (APD) routes are implemented industrially. Herein, how aging silica content affect the mechanical properties, these turn determine shrinkage, spring back, density during APD systematically investigated. The densities U-shaped dependence of w.r.t. concentration. At low concentrations, gels cannot withstand capillary forces dense xerogels obtained. intermediate to high shrinkage is strongly reduced increases A series cylinders prepared by SCD investigated uniaxial compression their strain recovery determined systematically. responses plastic, viscoelastic, brittle nature for low, intermediate, respectively. correlates degree back APD. viscoelastic response having 6 wt% corresponds concentration where minimum aerogel observed. importance gel mechanics APD, addition surface modification hydrophobization highlighted.
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ژورنال
عنوان ژورنال: Advanced Engineering Materials
سال: 2021
ISSN: ['1527-2648', '1438-1656']
DOI: https://doi.org/10.1002/adem.202100376